In this case preserving resolution matters because that scanned document shall get sent to a translator who should be able to print this true to scale.
Reproduction
1) Open in GraphicConverter (v12.0.1 build 6046) → File → Save for web…
2) Option "Reduce to 72 ppi" I left OFF.
3) I tried both with and without EXIF
Why it's worth fixing: In contrast to the available workaround (see below) the "Save for web" dialog gives you an instant visual preview of the chosen quality and sharpness. So it would be cool if that special dialog also preserved PPI resolution.
Workaround 1: You still have the original lossless image (e.g. TIFF)
1) Open parent folder in GraphicConverter Browser and select it.
2) Use quick convert to JPEG: Embed JFIF or EXIF.
Workaround 2: You only have the lossy image (e.g. JPEG)
• which is de facto your 600 PPI version (still has all the pixels of your scan @ 600 DPI)
• Only the resolution metadata falsely is 72 PPI, e.g. resulted from the "Save for web" bug
• No worry, there's a solution for this too: